Isothermal vs AdiabaticJEE Main

Two ways to expand the same gas — interactive Physics simulation for IIT-JEE.

Concept

Expand a gas the same amount two ways. Isothermal (slow, TT constant) keeps PVPV fixed. Adiabatic (fast, no heat) keeps PVγPV^\gamma fixed, so it falls more steeply and cools the gas. The work done — area under each P–V curve — differs.

Key formula

PV=const,Wiso=nRTlnV2V1;PVγ=const,Wadia=P1V1P2V2γ1PV = \text{const}, \quad W_{iso}=nRT\ln\frac{V_2}{V_1}; \qquad PV^\gamma=\text{const}, \quad W_{adia}=\frac{P_1V_1-P_2V_2}{\gamma-1}

Derivation

Isothermal: with TT fixed, ΔU=0\Delta U = 0, so by the first law Q=W=nRTln(V2/V1)Q = W = nRT\ln(V_2/V_1).

Adiabatic: Q=0Q = 0, so W=ΔU=nCv(T1T2)W = -\Delta U = nC_v(T_1 - T_2), which rearranges to (P1V1P2V2)/(γ1)(P_1V_1 - P_2V_2)/(\gamma-1). Because PVγPV^\gamma is constant, the adiabat is steeper than the isotherm and the gas does less work while expanding.

Scenarios to explore

  • Isothermal vs Adiabatic — Compare work done in two ways of expanding a gas.

Real-world applications

  • Diesel engine compression (adiabatic heating ignites fuel).
  • Cloud formation — rising air expands adiabatically and cools.
  • Sound propagation is an adiabatic, not isothermal, process (Laplace's correction).

JEE exam tips

  • For the same expansion, Wiso>WadiaW_{iso} > W_{adia} — the isotherm encloses more area.
  • Adiabatic relations: TVγ1=TV^{\gamma-1}= const and TγP1γ=T^\gamma P^{1-\gamma}= const.

Common mistakes

  • Using VV in litres for SI work — convert to m³ first.
  • Applying PV=PV = const to an adiabatic step (it is PVγPV^\gamma).
  • Forgetting an adiabatic expansion lowers temperature.

Exam traps to avoid

  • An adiabat is always steeper than the isotherm through the same point (slope ratio γ\gamma).
  • 'No heat exchange' (adiabatic) is not the same as 'constant temperature' (isothermal).