Bohr ModelJEE Main

Energy levels and spectral lines — interactive Physics simulation for IIT-JEE.

Concept

Bohr proposed electrons orbit the nucleus only in quantised energy levels En=13.6Z2/n2E_n = -13.6\,Z^2/n^2 eV. When an electron drops from a higher to a lower level, the energy difference leaves as a single photon, producing the sharp spectral lines we observe.

Key formula

En=13.6Z2n2eV,ΔE=13.6Z2 ⁣(1nf21ni2),rn=0.529n2ZA˚E_n = -\frac{13.6\,Z^2}{n^2}\,\text{eV}, \quad \Delta E = 13.6\,Z^2\!\left(\frac1{n_f^2}-\frac1{n_i^2}\right), \quad r_n = \frac{0.529\,n^2}{Z}\,\text{Å}

Derivation

Quantising angular momentum (mvr=nmvr = n\hbar) and balancing Coulomb attraction against the centripetal need gives discrete radii rnn2/Zr_n \propto n^2/Z and energies EnZ2/n2E_n \propto -Z^2/n^2.

A jump ninfn_i \to n_f releases ΔE=EiEf\Delta E = E_i - E_f. The photon wavelength follows from λ=hc/ΔE=1240/ΔE\lambda = hc/\Delta E = 1240/\Delta E nm. Final level nf=1,2,3n_f = 1,2,3 name the Lyman, Balmer and Paschen series.

Scenarios to explore

  • Bohr Model — Energy levels and the hydrogen spectral series.

Real-world applications

  • Explaining the hydrogen emission spectrum (Balmer's red Hα at 656 nm).
  • Atomic absorption/emission spectroscopy of stars.
  • Lasers and discharge lamps.

JEE exam tips

  • Ground state of hydrogen: E1=13.6E_1 = -13.6 eV, r1=0.529r_1 = 0.529 Å. Memorise these.
  • Ionisation energy from level nn is 13.6Z2/n213.6\,Z^2/n^2 eV.

Common mistakes

  • Forgetting the Z2Z^2 scaling for He⁺, Li²⁺ and other one-electron ions.
  • Sign errors — bound energies are negative; the photon energy is the positive difference.
  • Confusing the series (defined by nfn_f) with the individual lines (set by nin_i).

Exam traps to avoid

  • Largest wavelength in a series is the smallest-energy jump (nf+1nfn_f+1 \to n_f).
  • The Bohr model works only for one-electron (hydrogen-like) systems.